Silver siren! Angelina Jolie shows off her long legs in shimmering gown at 45th Annual Annie Awards in LA

Earlier in the week she met with NATO Secretary General Jens Stoltenberg.

But on Saturday Angelina Jolie was participating in a decidedly different endeavor, as she attended the Annie Awards, which recognize accomplishments in animation.

The Maleficent star, 42, looked stunning in her shiny silver gown as she traipsed down the red carpet.

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Back on the red carpet! On Saturday Angelina Jolie, 42, attended the Annie Awards, which recognize accomplishments in animation

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Back on the red carpet! On Saturday Angelina Jolie, 42, attended the Annie Awards, which recognize accomplishments in animation

The eye-catching frock featured a wrap-style sleeveless top, as well as a thigh-high split which gave a brief view of her toned legs.

In a practical twist, the garment also included some no doubt appreciated pockets.

Some very fashionable nude stiletto heels added several inches to her 5ft7in frame.

Accessories were limited to several sizable rings and very modest glittering earrings.

Angelina Jolie signs autographs outside of the Annie Awards

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Peek-a-boo! The eye-catching frock featured a wrap-style sleeveless top, as well as a thigh-high split which gave a brief view of her toned legs

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Peek-a-boo! The eye-catching frock featured a wrap-style sleeveless top, as well as a thigh-high split which gave a brief view of her toned legs

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View gallery

Peek-a-boo! The eye-catching frock featured a wrap-style sleeveless top, as well as a thigh-high split which gave a brief view of her toned legs

Enjoying herself! A smokey eye, subtle blush and a slick of brilliant crimson lipstick ensured the mother of six was glowing on the red carpet

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Enjoying herself! A smokey eye, subtle blush and a slick of brilliant crimson lipstick ensured the mother of six was glowing on the red carpet

Classic look: Her famous raven tresses were swept off her forehead and styled straight down her back as Zahara looked to be having a good time at the bash

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Classic look: Her famous raven tresses were swept off her forehead and styled straight down her back

Her famous raven tresses were swept off her forehead and styled straight down her back.

A smokey eye, subtle blush and a slick of brilliant crimson lipstick ensured the mother of six was glowing on the red carpet.

She was soon joined by two of her children for some snaps, daughter Shiloh, 11, and daughter Zahara, 13.

Shiloh kept things classic in black suit, while Zahara opted for a black blouse and trouser combination.

Finally! In a practical twist, the garment also included some no doubt appreciated pockets

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Finally! In a practical twist, the garment also included some no doubt appreciated pockets

Impressive! The animated film The Breadwinner, which details the struggle of a young girl in Taliban-era Afghanistan, managed to garner an impressive 10 Annie awards in several categories

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Impressive! The animated film The Breadwinner, which details the struggle of a young girl in Taliban-era Afghanistan, managed to garner an impressive 10 Annie awards in several categories

Breadwinner tells the story of a girl in Taliban-era Afghanistan

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Interestingly, the Oscar winner was on hand not because of a performance, but for a producing triumph.

The animated film The Breadwinner, which details the struggle of a young girl in Taliban-era Afghanistan, managed to garner an impressive 10 Annie awards in several categories.

The movie also caught the eye of the Academy, and is up for best Best Animated Feature Film in the upcoming 2018 edition of the awards show.

In addition to the Nato Security General, Angelina also met with France’s First Lady Brigitte Macron in Paris to discuss her visit and urge members of the UN Security Council to resolve the conflict in Syria.

Proud mom! She was soon joined by two of her children for some snaps, daughter Shiloh, 11, and daughter Zahara, 13, at the 2018 Annie Awards, which was held at the Los Angeles venue Royce Hall

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Proud mom! She was soon joined by two of her children for some snaps, daughter Shiloh, 11, and daughter Zahara, 13

Doting mum: Brad Pitt's ex-wife wrapped her arm around Shiloh at the awards night as she juggled promoting her acting career with being a mum

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Doting mum: Brad Pitt’s ex-wife wrapped her arm around Shiloh at the awards night as she juggled promoting her acting career with being a mum

Pin-credible style: The long trailing silver garment featured a soaring split to showcase her slender legs and she commanded further attention with her sky-scraper nude heels

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Pin-credible style: The long trailing silver garment featured a soaring split to showcase her slender legs and she commanded further attention with her sky-scraper nude heels

Proud mom! Angelina looked upon her daughter with adoring eyes as they mingled with a whole host of Hollywood's elite at the event

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A mother’s gaze! Angelina looked upon her daughter with adoring eyes as they mingled with a whole host of Hollywood’s elite at the event

Inside the venue: The mother and daughter showed their close bond as they looked at one another with the same adoring gaze

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Inside the venue: The mother and daughter showed their close bond as they looked at one another with the same adoring gaze

A mother's affection: Angelina couldn't hide her pride as she beamed brightly while she set her sights on her daughter

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A mother’s affection: Angelina couldn’t hide her pride as she beamed brightly while she set her sights on her daughter

Leading lady: Angelina held the hands of her two children Shiloh and Zahara on the red carpet when they finished posing for photographs

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Leading lady: Angelina held the hands of her two children Shiloh and Zahara on the red carpet when they finished posing for photographs

Looking incredible: Angelina stood out from the crowd on the red carpet in her glistening silver pleated gown which perfectly framed her lovely figure

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Looking incredible: Angelina stood out from the crowd on the red carpet in her glistening silver pleated gown which perfectly framed her lovely figure

Best of both worlds: Angelina brought two of her children onto the red carpet as she promoted the movie with director Nora Twomey (L) and actress Saara Chaudry (R) 

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Best of both worlds: Angelina brought two of her children onto the red carpet as she promoted the movie with her co-star and director

Photo opportunity! Of course Angelia rubbed shoulders with Twomey on the red carpet

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Photo opportunity! Of course Angelia rubbed shoulders with Director Nora Twomey on the red carpet

Loving lady: The age-defying beauty rested her arm affectionately on the rising star Chaudry's shoulder at the occasion

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Loving lady: The age-defying beauty rested her arm affectionately on the rising star Saara Chaudry’s shoulder at the occasion

Pleasing beauty: Angelina was delighted to pose with Saar Chaudry (L) on the red carpet

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Pleasing beauty: Angelina was delighted to pose with Saar Chaudry (L) on the red carpet

Pout and about: The Tomb Raider star added a pop of colour to her silver siren looks with a shade of striking scarlet lipstick

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Pout and about: The Tomb Raider star added a pop of colour to her silver siren looks with a shade of striking scarlet lipstick

Signing away! The film star was every inch the socialite when she signed autographs for people at the glitzy occasion

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Signing away! The film star was every inch the socialite when she signed autographs for people at the glitzy occasion

Age-defying: The sensational woman looked incredibly youthful, with the help of deftly touches of make-up and styling her gorgeous brunette tresses

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Age-defying: The sensational woman looked incredibly youthful, with the help of deftly touches of make-up and styling her gorgeous brunette tresses

Wow: The Hollywood queen looked stunning in a plunging silver dress which was nipped at the waist to accentuate her petite waistline

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Wow: The Hollywood queen looked stunning in a plunging silver dress which was nipped at the waist to accentuate her petite waistline

She's got style: Angelina showcased her intimate inkings on her arms when she partied up a storm at the Annie Awards in Los Angeles

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She’s got style: Angelina showcased her intimate inkings on her arms when she partied up a storm at the Annie Awards in Los Angeles

Show-stopping: The cast were delighted as the movie also caught the eye of the Academy, and is up for best Best Animated Feature Film in the upcoming 2018 edition of the awards show

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Show-stopping: The cast were delighted as the movie also caught the eye of the Academy, and is up for best Best Animated Feature Film in the upcoming 2018 edition of the awards show

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